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521.
Manganese oxides precipitated from aerated well sea water at the Marine Science Museum, Tokai University, have been analyzed chemically and mineralogically. The OMn ratios are lower in todorokite than in birnessite but these minerals have similar contents of minor transition metals, which can be taken up additionally from sea water after the precipitation of Mn oxides. On the basis of these results, the genesis of Mn minerals is discussed in relation to marine Mn nodules.  相似文献   
522.
Powell's method for minimizing a function of several variables without calculating derivatives is applied to recorded earthquake motion on the ground surface to identify ground characteristics that have irregular profiles. The identifications are made by designating the shear wave velocity depth and width of the irregularity of surface ground as unknown parameters and are based on the least square fit between the amplitude of the transfer function determined from accelerograms recorded at two observation sites and the corresponding transfer function calculated from the response analysis of a ground model. The discrete wave number method is used to analyze the response of ground with a non-uniform profile for the incidence of SH waves. The effect of the initial assumed values on the convergence is studied by evaluating the square error between the theoretical transfer function and that calculated from the parameters identified. The dispersive trend found for the accelerograms is explained by the calculated response of a ground model with a non-uniform profile.  相似文献   
523.
This paper presents an approach to the problem of separation and sliding between soil and structure in the finite element analysis of dynamic soil-structure interaction problems. Joint elements are arranged along the contact surface between soil and structure and they have a property such that tensile forces are not transmitted between the planes representing structure and soil in the finite element analysis. The dynamic properties governing the sliding are determined by the Mohr-Coulomb failure law determined from the cohesion and the friction angle between soil and structure. The proposed method is applied to (i) a model of a reactor building resting on the free surface of layered ground and (ii) a buried foundation structure. The numerical computations reveal the following results: that the translation is dominant in the motion of the structure when sliding is taking place between soil and structure, and that the rocking is dominant in the rest of the response. The amplitude of the response during sliding is increased on any one point of the structure and decreased on any one point of the ground compared with that of the fixed condition at the interface. In the case of the buried structure, it is observed in the computed results that the structure and soil move in the opposite direction along the vertical contact surface and are separated from each other in the near surface region during the strong phase of the excitation.  相似文献   
524.
On the basis of observations using Cs‐corrected STEM, we identified three types of surface modification probably formed by space weathering on the surfaces of Itokawa particles. They are (1) redeposition rims (2–3 nm), (2) composite rims (30–60 nm), and (3) composite vesicular rims (60–80 nm). These rims are characterized by a combination of three zones. Zone I occupies the outermost part of the surface modification, which contains elements that are not included in the unchanged substrate minerals, suggesting that this zone is composed of sputter deposits and/or impact vapor deposits originating from the surrounding minerals. Redeposition rims are composed only of Zone I and directly attaches to the unchanged minerals (Zone III). Zone I of composite and composite vesicular rims often contains nanophase (Fe,Mg)S. The composite rims and the composite vesicular rims have a two‐layered structure: a combination of Zone I and Zone II, below which Zone III exists. Zone II is the partially amorphized zone. Zone II of ferromagnesian silicates contains abundant nanophase Fe. Radiation‐induced segregation and in situ reduction are the most plausible mechanisms to form nanophase Fe in Zone II. Their lattice fringes indicate that they contain metallic iron, which probably causes the reddening of the reflectance spectra of Itokawa. Zone II of the composite vesicular rims contains vesicles. The vesicles in Zone II were probably formed by segregation of solar wind He implanted in this zone. The textures strongly suggest that solar wind irradiation damage and implantation are the major causes of surface modification and space weathering on Itokawa.  相似文献   
525.
The mineralogy and mineral chemistry of Itokawa dust particles captured during the first and second touchdowns on the MUSES‐C Regio were characterized by synchrotron‐radiation X‐ray diffraction and field‐emission electron microprobe analysis. Olivine and low‐ and high‐Ca pyroxene, plagioclase, and merrillite compositions of the first‐touchdown particles are similar to those of the second‐touchdown particles. The two touchdown sites are separated by approximately 100 meters and therefore the similarity suggests that MUSES‐C Regio is covered with dust particles of uniform mineral chemistry of LL chondrites. Quantitative compositional properties of 48 dust particles, including both first‐ and second‐touchdown samples, indicate that dust particles of MUSES‐C Regio have experienced prolonged thermal metamorphism, but they are not fully equilibrated in terms of chemical composition. This suggests that MUSES‐C particles were heated in a single asteroid at different temperatures. During slow cooling from a peak temperature of approximately 800 °C, chemical compositions of plagioclase and K‐feldspar seem to have been modified: Ab and Or contents changed during cooling, but An did not. This compositional modification is reproduced by a numerical simulation that modeled the cooling process of a 50 km sized Itokawa parent asteroid. After cooling, some particles have been heavily impacted and heated, which resulted in heterogeneous distributions of Na and K within plagioclase crystals. Impact‐induced chemical modification of plagioclase was verified by a comparison to a shock vein in the Kilabo LL6 ordinary chondrite where Na‐K distributions of plagioclase have been disturbed.  相似文献   
526.
Performance of a regional climate model (RCM), WRF, for downscaling East Asian summer season climate is investigated based on 11-summer integrations associated with different climate conditions with reanalysis data as the lateral boundary conditions. It is found that while the RCM is essentially unable to improve large-scale circulation patterns in the upper troposphere for most years, it is able to simulate better lower-level meridional moisture transport in the East Asian summer monsoon. For precipitation downscaling, the RCM produces more realistic magnitude of the interannual variation in most areas of East Asia than that in the reanalysis. Furthermore, the RCM significantly improves the spatial pattern of summer rainfall over dry inland areas and mountainous areas, such as Mongolia and the Tibetan Plateau. Meanwhile, it reduces the wet bias over southeast China. Over Mongolia, however, the performance of precipitation downscaling strongly depends on the year: the WRF is skillful for normal and wet years, but not for dry years, which suggests that land surface processes play an important role in downscaling ability. Over the dry area of North China, the WRF shows the worst performance. Additional sensitivity experiments testing land effects in downscaling suggest the initial soil moisture condition and representation of land surface processes with different schemes are sources of uncertainty for precipitation downscaling. Correction of initial soil moisture using the climatology dataset from GSWP-2 is a useful approach to robustly reducing wet bias in inland areas as well as to improve spatial distribution of precipitation. Despite the improvement on RCM downscaling, regional analyses reveal that accurate simulation of precipitation over East China, where the precipitation pattern is strongly influenced by the activity of the Meiyu/Baiu rainfall band, is difficult. Since the location of the rainfall band is closely associated with both lower-level meridional moisture transport and upper-level circulation structures, it is necessary to have realistic upper-air circulation patterns in the RCM as well as lower-level moisture transport in order to improve the circulation-associated convective rainfall band in East Asia.  相似文献   
527.
This study compares the synoptic-dynamic relationship between two phases of the Pacific/North American (PNA) pattern and winter precipitation isotopes at 73 sites across the contiguous USA. We use the spatial pattern of isotope slope—the rate of changes in precipitation isotope ratios with distance—to identify features in the seasonal precipitation isotope fields related to climatic patterns, PNA positive and PNA negative. Our results show relationships between zones of high isotope slopes and the spatial position of the polar jet stream and juxtaposition of air masses associated with the PNA pattern. During a positive PNA winter, zones of high isotope slope in the eastern USA shift southward. This change is coincident with a southward displacement of the polar jet stream in this region, which leads to a greater frequency of polar air masses and 18O-depleted isotope values of precipitation in the region. In the western USA, zones of high slope shift eastward during the positive PNA winter, associated with more frequent penetration of tropical air masses that bring 18O-enriched precipitation to the region. Differences in δ18O/temperature relationships between the PNA-positive and -negative winters and contrasting δ18O/temperature behaviors in the eastern and western USA provide support for the role of variation in moisture source and transport as a control on the isotopic patterns. These findings highlight the importance of synoptic climate driven by PNA pattern in determining the spatial patterns of precipitation isotopes and provide constraints on paleo-water isotope interpretation and modern isotope hydrological processes.  相似文献   
528.
529.
Mining operations in the Pinpet Fe deposit, which is the second‐largest Fe deposit in Myanmar, are currently suspended, in part because of possible contamination of heavy metals and hazardous elements (e.g., Fe, As, Cu, Zn, and U) into the surrounding aquatic environment and associated public concern. However, a scientific investigation of the source and degree of contamination in streams near the deposit has not yet been conducted. Therefore, we quantified heavy‐metal and hazardous‐element concentrations of stream waters and sediments in stream beds, and measured the speciation and concentration of these metals in deposit Fe ores using the sequential extraction method, to better understand the influence of mining activities on the surrounding environment. Geochemical results for Nan‐tank‐pauk stream and its tributaries indicate that the chemical compositions of their waters are controlled by carbonate bedrock and that no detectable contamination has occurred as a result of mining activity or hematite and limonite ore beneficiation processes in either the wet or dry seasons. All measured heavy‐metal and hazardous‐element concentrations were below the World Health Organization standards for drinking water and the proposed national drinking water quality standards in Myanmar. Bulk chemical compositions of stream‐bed and tailings dam sediments show that As, Zn, and Cu concentrations are similar to those in uncontaminated sediments. Results of bulk mineralogical and chemical analyses of ore samples reveal that some limonite ore samples contain substantial amounts of As (up to 2 wt%). However, sequential extraction results indicate that most (>90%) of the As in these As‐rich ores is hosted in insoluble fractions (e.g., crystalline Fe hydroxides and clays). Therefore, arsenic is unlikely to be released into the aquatic environment by interacting with water during ore beneficiation processes should the mine resume operations.  相似文献   
530.
Hirose  Nariaki  Usui  Norihisa  Sakamoto  Kei  Tsujino  Hiroyuki  Yamanaka  Goro  Nakano  Hideyuki  Urakawa  Shogo  Toyoda  Takahiro  Fujii  Yosuke  Kohno  Nadao 《Ocean Dynamics》2019,69(11):1333-1357

We developed a new system to monitor and forecast coastal and open-ocean states around Japan for operational use by the Japan Meteorological Agency. The system consists of an eddy-resolving analysis model based on four-dimensional variational assimilation and a high (2-km) resolution forecast model covering Japanese coastal areas that incorporates an initialization scheme with temporal and spatial filtering. Assimilation and forecast experiments were performed for 2008 to 2017, and the results were validated against various observation datasets. The assimilation results captured well the observed variability in sea surface temperature, coastal sea level, volume transport, and sea ice. Furthermore, the volume budget for the Japan Sea was significantly improved by the use of the 2-km resolution forecast model compared with the 10-km resolution analysis model. The forecast results indicate that this system has a predictive limit longer than 1 month in many areas, including in the Kuroshio current area south of Japan and the southern Japan Sea. In the forecast results of case studies, the 2017 Kuroshio large meander was well predicted, and warm water intrusions accompanying Kuroshio path variations south of Japan were also successfully reproduced. Sea ice forecasts for the Sea of Okhotsk largely captured the evolution of sea ice in late winter, but sea ice in early winter included relatively large errors. This system has high potential to meet operational requirements for monitoring and forecasting ocean phenomena at both meso- and coastal scales.

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